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The first mol­ecular compound synthesized and crystallized in Benin is reported. This work was carried out during the first crystallographic training session at the X-TechLab in Sèmè City, organized within the IUCr–UNESCO OpenLab framework.

Crystal structure of a new phenyl(morpholino)methanethione derivative: 4-[(morpholin-4-yl)carbothioyl]benzoic acid