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Solid-state structures of the title compounds are presented to show the relative effects of 1,3,5-tri­aza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-tri­aza-5-phosphabi­cyclo­[3.3.1]nonane (DAPTA) ligands on the mol­ecular and extended structure.

acta crystallographica section e crystallographic communications

Crystal structures of trans-acetyldicarbonyl(η5-cyclopentadienyl)(1,3,5-triaza-7-phosphaadamantane)molybdenum(II) and trans-acetyldicarbonyl(η5-cyclopentadienyl)(3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)molybdenum(II)