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In the crystal of the title compound, the packing is driven by O—H⋯O, O—H⋯N and N—H⋯N hydrogen-bond inter­actions along with π–π stacking inter­actions.

Crystal structure and Hirshfeld surface analysis of 3,6-bis(pyrimidin-2-yl)-1,4-dihydro-1,2,4,5-tetrazine dihydrate