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A coordination polymer formulated as [Sr(H 2 BTEC)(H 2 O)]  n  (H 4 BTEC = benzene-1,2,4,5-tetra-carb-oxy-lic acid, C 10 H 6 O 8 ), was synthesized hydro-thermally and characterized by single-crystal and powder X-ray diffraction, scanning electron microscopy and thermal analysis. Its crystal structure is made up of a zigzag inorganic chain formed by edge-sharing of [SrO 8 ] polyhedra running along [001]. Adjacent chains are connected to each other via the carboxyl-ate groups of the ligand, resulting in a double-layered network extending parallel to (100). O-H⋯O hydrogen bonds of medium-to-weak strength between the layers consolidate the three-dimensional structure. One of the carb-oxy-lic OH functions was found to be disordered over two sets of sites with half-occupancy.

Synthesis, crystal structure, and thermal properties of poly[aqua(μ5-2,5-dicarboxybenzene-1,4-dicarboxylato)strontium]

Synthesis, crystal structure, and thermal properties of poly[aqua(μ₅-2,5-dicarboxybenzene-1,4-dicarboxylato)strontium]