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Deuterated potassium orthophosphate hepta-hydrate, K 3 PO 4 ·7D 2 O, crystallizes in the Sohnke space group P 2 1 , and its absolute structure was determined from 2017 Friedel pairs [Flack parameter 0.004 (16)]. Each of the three crystallographically unique K + cations is surrounded by six water mol-ecules and one oxygen atom from the orthophosphate group, using a threshold for K-O bonds of 3.10 Å. The highly irregular coordination polyhedra are linked by corner- and edge-sharing into a three-dimensional network that is consolidated by an intricate network of O-D⋯O hydrogen bonds of medium strength.

Crystal structure of the deuterated heptahydrate of potassium phosphate, K3PO4·7D2O

Crystal structure of the deuterated heptahydrate of potassium phosphate, K₃PO₄·7D₂O