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In the title compound, di-μ-cyanato-1:2κ 2  N : C ;2:3κ 2  C : N -di-cyanato-2κ 2  C -bis-(1,4,7,10,13,16-hexa-oxa-cyclo-octa-deca-ne)-1κ 6  O ;3κ 6  O -1,3-dipotassium(I)-2-platinum(II), [K 2 Pt(CN) 4 (C 12 H 24 O 6 ) 2 ] or [K(18-crown-6)] 2 ·[Pt(CN) 4 ], two trans -orientated cyano groups of the square-planar [Pt(CN) 4 ] 2- dianion (Pt site symmetry ) bind to one potassium ion each, which are additionally coordinated by the six O atoms of 18-crown-6. No Pt⋯Pt inter-actions occur in the crystal, but very weak Pt⋯H contacts (2.79 Å) are observed.

Crystal structure of [K(18-crown-6)]+2[Pt(CN)4]2−

Crystal structure of [K(18-crown-6)]⁺₂[Pt(CN)₄]²⁻