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The title compound, C 14 H 14 N 2 S 2 , was obtained by transmetallation of 2,2'-bis-(tri-methyl-stann-yl)azo-benzene with methyl lithium, and subsequent quenching with dimethyl di-sulfide. The asymmetric unit comprises two half-mol-ecules, the other halves being completed by inversion symmetry at the midpoint of the azo group. The two mol-ecules show only slight differences with respect to N=N, S-N and aromatic C=C bonds or angles. Hirshfeld surface analysis reveals that except for one weak H⋯S inter-action, inter-molecular inter-actions are dominated by van der Waals forces only.

Synthesis and crystal structure of (E)-1,2-bis[2-(methylsulfanyl)phenyl]diazene