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In the title com-pound, C 20 H 26 N 2 O 9 S, the S atom is attached equatorially to the sugar ring. The C-S bond lengths are unequal, with S-C s = 1.8018 (13) Å and S-C p = 1.7662 (13) Å (s = sugar and p = pyrimid-yl). In the crystal, a system of three weak hydrogen bonds, sharing an oxygen acceptor, links the mol-ecules to form chains propagating parallel to the b -axis direction.

Crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)sulfanyl]pyrimidine