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In the title polymeric complex, {[FePt(CN) 4 (H 2 O) 2 ]·2C 3 H 6 O}  n  , the Fe II cation has an octa-hedral [FeN 4 O 2 ] geometry being coordinated by two water mol-ecules and four cyanide anions. The Pt cation is located on an inversion centre and has a square-planar coordination environment formed by four cyanide groups. The tetra-cyano-platinate anions bridge the Fe II cations to form infinite two-dimensional layers that propagate in the bc plane. Two guest mol-ecules of acetone per Fe II are located between the layers. These guest acetone mol-ecules inter-act with the coordinated water mol-ecules by O-H⋯O hydrogen bonds.

Crystal structure of poly[[diaquatetra-μ2-cyanido-iron(II)platinum(II)] acetone disolvate]

Crystal structure of poly[[diaquatetra-μ₂-cyanido-iron(II)platinum(II)] acetone disolvate]