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Bidentate and tridentate coordination of a 2,4-di- tert -butyl-substituted bridging amine bis-(phenolate) ligand to a palladium(II) center are observed within the same crystal structure, namely di-chlorido-({6,6'-[(ethane-1,2-diylbis(methyl-aza-nedi-yl)]bis-(methyl-ene)}bis-(2,4-di- tert -butyl-phenol))palladium(II) chlorido-(2,4-di- tert -butyl-6-{[(2-{[(3,5-di- tert -butyl-2-hy-droxy-phen-yl)meth-yl](meth-yl)amino}-eth-yl)(meth-yl)amino]-meth-yl}phenolato)palladium(II) methanol 1.685-solvate 0.315-hydrate, [PdCl 2 (C 34 H 56 N 2 O 2 )][PdCl(C 34 H 55 N 2 O 2 )]·1.685CH 3 OH·0.315H 2 O. Both complexes exhibit a square-planar geometry, with unbound phenol moieties participating in inter-molecular hydrogen bonding with co-crystallized water and methanol. The presence of both κ 2 and κ 3 coordination modes arising from the same solution suggest a dynamic process in which phenol donors may coordinate or dissociate from the metal center, and offers insight into catalyst speciation throughout Pd-mediated processes. The unit cell contains di-chlorido-({6,6'-[(ethane-1,2-diylbis(methyl-aza-nedi-yl)]bis-(methyl-ene)}bis-(2,4-di- tert -butyl-phenol))palladium(II), {( L  2 )PdCl 2 }, and chlorido-(2,4-di- tert -butyl-6-{[(2-{[(3,5-di- tert -butyl-2-hy-droxy-phen-yl)meth-yl](methyl)amino}eth-yl)(meth-yl)amino]-meth-yl}phenolato)palladium(II), {( L  2  X )PdCl}, mol-ecules as well as fractional water and methanol solvent mol-ecules.

Palladium(II) complexes of a bridging amine bis(phenolate) ligand featuring κ2 and κ3 coordination modes

Palladium(II) complexes of a bridging amine bis(phenolate) ligand featuring κ² and κ³ coordination modes