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The asymmetric unit of the title compound, C 12 H 22 N + ·CH 3 O 3 S - , consists of three (3,5-di-methyl-adamantan-1-yl)ammonium cations, C 12 H 22 N + , and three methane-sulfonate anions, CH 3 O 3 S - . In the crystal, the cations and anions associate via N-H⋯O hydrogen bonds into layers, parallel to the (001) plane, which include large supra-molecular hydrogen-bonded rings.

(3,5-Dimethyladamantan-1-yl)ammonium methanesulfonate (memantinium mesylate): synthesis, structure and solid-state properties