English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

The crystal structure of the title compound, [Ni(C 63 H 31 F 10 N 5 S 2 )]· x CH 2 Cl 2 ( x &gt; 1/2), consists of Ni-porphyrin complexes that are located in general positions and di-chloro-methane solvent mol-ecules that are disordered around centers of inversion. The Ni II ions are in a square-pyramidal (CN5) coordination, with four porphyrin N atoms in the equatorial and a pyridine N atom in the apical position and are shifted out of the porphyrine N 4 plane towards the coordinating pyridine N atom. The pyridine substituent is not exactly perpendicular to the N 4 plane with an angle of inter-section between the planes planes of 80.48 (6)°. The di-chloro-methane solvent mol-ecules are hydrogen bonded to one of the four porphyrine N atoms. Two complexes are linked into dimers by two symmetry-equivalent C-H⋯S hydrogen bonds. These dimers are closely packed, leading to cavities in which additional di-chloro-methane solvent mol-ecules are embedded. These solvent mol-ecules are disordered and because no reasonable split model was found, the data were corrected for disordered solvent using the PLATON SQUEEZE routine [Spek (2015 ▸). Acta Cryst. C 71 , 9-18].

acta crystallographica. section e, crystallographic communications

Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(pyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1′-biphenyl]-4′,2-diyl]}porphyrinato)nickel(II) dichloromethane <i>x</i>-solvate (<i>x</i> &gt; 1/2) showing a rare CN5 coordination

Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(pyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1′-biphenyl]-4′,2-diyl]}porphyrinato)nickel(II) dichloromethane x-solvate (x > 1/2) showing a rare CN5 coordination