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The structures of two isomers of the title compound, [RuCl 2 (C 14 H 12 N 4 )(C 2 H 6 OS) 2 ], 2 and 3 , are reported. Isomers 2 and 3 are produced by reaction of the pyridyl-triazole ligand 1-benzyl-4-(pyridin-2-yl)-1 H -1,2,3-triazole (bpt) ( 1 ) with fac -[RuCl 2 (DMSO- S ) 3 (DMSO- O )]. Reaction in acetone produces ca 95% 2 , which is the OC -6-14 isomer, with cis DMSO and trans chlorido ligands, and 5% 3 (the OC -6-32 isomer, with cis DMSO and cis chlorido ligands, and the pyridyl moiety of bpt trans to DMSO). Reaction in refluxing toluene initially forms 2 , which slowly isomerizes to 3 .

acta crystallographica. section e, crystallographic communications

Two isomers of [1-benzyl-4-(pyridin-2-yl-κN)-1H-1,2,3-triazole-κN 3]dichloridobis(dimethyl sulfoxide-κS)ruthenium(II)