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The title binuclear Co III complex, [Co 2 (C 9 H 8 BrNOS) 2 (C 18 H 16 Br 2 N 2 O 2 S 2 )]·C 3 H 7 NO, with a Schiff base ligand formed in situ from cyste-amine (2-amino-ethane-thiol) and 5-bromo-salicyl-aldehyde crystallizes in the space group P 2 1 . It was found that during the synthesis the ligand undergoes spontaneous oxidation, forming the new ligand H 2  L ' having an S-S bond. Thus, the asymmetric unit consists of one Co 2 ( L ) 2 ( L ') mol-ecule and one DMF solvent mol-ecule. Each Co III ion has a slightly distorted octa-hedral S 2 N 2 O 2 coordination geometry. In the crystal, the components are linked into a three-dimensional network by several S⋯ Br, C⋯ Br, C-H⋯Br, short S⋯C (essentially shorter than the sum of the van der Waals radii for the atoms involved) contacts as well by weak C-H⋯O hydrogen bonds. The crystal studied was refined as an inversion twin.

acta crystallographica. section e, crystallographic communications

Crystal structure of bis(μ-{2-[(5-bromo-2-oxidobenzylidene)amino]ethyl}sulfanido-κ3 N,O,S){2,2′-[(3,4-dithiahexane-1,6-diyl)bis(nitrilomethanylylidene)]bis(4-bromophenolato)-κ4 O,N,N′,O′}dicobalt(III) dimethylformamide monosolvate