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In the title 1:1 co-crystal, [Cu(C 24 H 24 N 8 O 6 )]·C 11 H 11 N 3 O 4 , each of the crystal components forms undulating layers which stack alternately along the b- axis direction. Mol-ecules of the Cu II complex are connected via C-H⋯O hydrogen bonds involving the nitro and keto oxygen atoms, thus forming supra-molecular networks. Mol-ecules of the aryl-hydrazone component are linked by C-H⋯O inter-actions into zigzag strands showing no inter-strand association.

acta crystallographica. section e, crystallographic communications

Crystal structure of (N,N′-ethylenebis{3-[2-(3-nitrophenyl)hydrazin-1-ylidene]-4-oxopentan-2-iminato})copper(II)–3-[2-(3-nitrophenyl)hydrazin-1-ylidene]pentane-2,4-dione (1/1)