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The title trinuclear nickel(II) complex, [Ni 3 (C 10 H 11 NO 2 S) 3 ]·C 3 H 7 NO, with a Schiff base ligand formed in situ from 2-amino-ethane-thiol and o -vanillin crystallizes in the ortho-rhom-bic space group Pbca . Its asymmetric unit consists of one neutral Ni 3  L  3 mol-ecule and one DMF solvent mol-ecule. The solid-state organization of the complex can be described as an insertion of the solvent mol-ecules within the crystallographically independent trinuclear Ni II species. Several C-H⋯π edge-to-face inter-actions and π-π stacking inter-actions link the components in the crystal. A first example of a short inter-molecular C-H⋯Ni contact is found. Anti-bacterial in vitro screening revealed that the title compound has anti-bacterial activity, the best effect being against Acinetobacter baumannii .

acta crystallographica. section e, crystallographic communications

Tris(μ<sub>2</sub>-2-methoxy-6-{[(2-sulfidoethyl)imino]methyl}phenolato)trinickel(II) dimethylformamide monosolvate: crystal structure, spectroscopic characterization and antibacterial activity

Tris(μ2-2-methoxy-6-{[(2-sulfidoethyl)imino]methyl}phenolato)trinickel(II) dimethylformamide monosolvate: crystal structure, spectroscopic characterization and antibacterial activity

Tris(μ₂-2-methoxy-6-{[(2-sulfidoethyl)imino]methyl}phenolato)trinickel(II) dimethylformamide monosolvate: crystal structure, spectroscopic characterization and antibacterial activity