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In the title salt, {[Li(C 2 H 5 NO 2 ) 2 ]ClO 4 }  n  , the Li + cation is coordinated by four carboxyl-ate oxygen atoms of the glycine mol-ecules with a distorted tetra-hedral geometry. The glycine exists in a zwitterionic form with protonated amino and deprotonated carboxyl-ate groups. In the crystalline state, the title salt is primarily stabilized by inter-molecular N-H⋯O and C α -H⋯O inter-actions which inter-connect various units. Hirshfeld surface analysis indicates that the inter-molecular H⋯O/O⋯H inter-actions are the most important contributors to the crystal packing.

Crystal structure and Hirshfeld surface analysis of poly[[di-μ3-glycine-lithium] perchlorate]

Crystal structure and Hirshfeld surface analysis of poly[[di-μ₃-glycine-lithium] perchlorate]