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The title compound, [Mn 2 (C 4 H 5 N 2 O 4 ) 2 (NCS) 2 (H 2 O) 4 ]·4H 2 O (I), exists as a centrosymmetric dimer. Each dimeric unit consists of tridentate ( O , O , N )-chelating Schiff bases with symmetry-maintained μ- O -bridged carboxyl-ate anions, terminally bound thio-cyanate anions, and ligated and solvated water mol-ecules. The complex exhibits a distorted octa-hedron geometry and the centrosymmetric μ- O -bridged carboxyl-ate anions connect the two manganese atoms to form an M  2 O 2 ring. In the crystal, the mol-ecules are inter-linked via strong N-H⋯O and O-H⋯O hydrogen-bonding contacts and weak O-H⋯S inter-molecular inter-actions, forming a three-dimensional mol-ecular network.

acta crystallographica. section e, crystallographic communications

Crystal structure and thermal properties of bis[μ-2-(methoxycarbonylhydrazinylidene)acetato-κ3 N 1,O:O]bis[diaqua(thiocyanato-κN)manganese(II)] tetrahydrate