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The asymmetric unit of the title compound, fac -[Ir(C 11 H 8 N) 2 (C 18 H 24 N 2 )]Cl or fac -[Ir(ppy) 2 (Hppy-NC 6 )]Cl, contains two [Ir(ppy) 2 (ppy-NC 6 )](H + ) cations, two Cl - anions and disordered solvent. In each complex mol-ecule, the Ir III ion is coordinated by two C , N -bidentate 2-(pyridin-2-yl)phenyl ligands and one C , N -bidentate N -[4-(pyridin-2-yl)benz-yl]hexan-1-aminium ligand, leading to a distorted fac -octa-hedral coordination environment. In the crystal, the mol-ecules are linked by N-H⋯Cl, C-H⋯π and π-π inter-actions, forming a three-dimensional supra-molecular structure. The hexyl group of one mol-ecule is disordered over two orientations with a refined occupancy ratio of 0.412 (13):0.588 (13). The acetone and hexane solvent mol-ecules were found to be highly disordered and their contribution to the scattering was masked using the solvent-masking routine smtbx.mask in OLEX2 [Rees et al. (2005 ▸). Acta Cryst . D 61 , 1299-1301]. These solvent mol-ecules are not considered in the given chemical formula and other crystal data.

acta crystallographica. section e, crystallographic communications

Crystal structure of fac-{5-[(hexylazaniumyl)methyl]-2-(pyridin-2-yl)phenyl-κ2 N,C 1}bis[2-(pyridin-2-yl)phenyl-κ2 N,C 1]iridium(III) chloride