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The title cluster compound, [Ru 3 (C 19 H 17 PS)(CO) 11 ], comprises a triangle of Ru 0 atoms, two of which are bonded to four carbonyl ligands. The third metal atom is bound to three carbonyl ligands and the phosphane-P atom of a dissymmetric phosphane ligand, PPh 2 (C 6 H 4 SMe-4); no Ru⋯S inter-actions are observed. The phosphane occupies an equatorial position and its proximity to an Ru-Ru edge results in the elongation of this bond with respect to the others [2.8933 (2) Å cf . 2.8575 (2) and 2.8594 (3) Å]. In the crystal, phenyl-C-H⋯O(carbon-yl) and carbonyl-O⋯O(carbon-yl) [2.817 (2) Å] inter-actions combine to form a supra-molecular chain propagating along [111]; the chains pack without directional inter-actions between them. The carbonyl-O⋯O(carbon-yl) and other weak contacts have an influence upon the Hirshfeld surfaces with O⋯H contacts making the greatest contribution, i.e . 37.4% cf . 15.8% for O⋯O and 15.6% for H⋯H contacts.

Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): crystal structure and Hirshfeld surface analysis