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3-(1,1,1-Tri-methyl-hydrazin-1-ium-2-yl)propano-ate (C 6 H 14 N 2 O 2 , M , more commonly known under its commercial names Meldonium or Mildronate ) co-crystalizes with sodium bromide and sodium iodide forming polymeric hydrates poly[[tetra-μ-aqua-di-aqua-bis-[3-(1,1,1-tri-methyl-hydrazin-1-ium-2-yl)propano-ate]disodium] dibromide tetra-hydrate], [Na 2 (C 6 H 14 N 2 O 2 ) 2 (H 2 O) 6 ]Br 2 ·4H 2 O, and poly[[di-μ-aqua-di-aqua-[μ-3-(1,1,1-tri-methyl-hydrazin-1-ium-2-yl)propano-ate]disodium] diiodide], [Na 2 (C 6 H 14 N 2 O 2 ) 2 (H 2 O) 4 ]I 2 . The coordination numbers of the sodium ions are 6; the coordination polyhedra can be described as distorted octa-hedra. Metal ions and M zwitterions are assembled into infinite layers via electrostatic inter-actions and hydrogen-bonded networks. These layers are connected via electrostatic attraction between halogenide ions and positive tri-methyl-hydrazinium groups into a three-dimensional structure.

Crystal structures of binary compounds of meldonium 3-(1,1,1-trimethylhydrazin-1-ium-2-yl)propanoate with sodium bromide and sodium iodide