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The crystal and mol-ecular structures of two tri-phenyl-tin di-thio-carbamate compounds, viz . [Sn(C 6 H 5 ) 3 (C 8 H 16 NS 2 )], (I), and [Sn(C 6 H 5 ) 3 (C 10 H 12 NS 2 )], (II), are described. The di-thio-carbamate ligand in each mol-ecule coordinates in an asymmetric fashion resulting in heavily distorted tetra-hedral C 3 S coordin-ation geometries for the Sn atoms, with the distortions traced to the close approach of the non-coordinating thione-S atom. The mol-ecular packing in both compounds features C-H⋯π(Sn-phen-yl) inter-actions. In (I), the donors are Sn-phenyl-C-H groups leading to centrosymmetric aggregates, while in (II), the donors are both Sn-phenyl-C-H and methyl-C-H groups leading to supra-molecular chains propagating along the b axis. The identified aggregates assemble into their respective crystals with no directional inter-actions between them. An analysis of the Hirshfeld surfaces show distinctive patterns, but an overwhelming predominance (&gt;99% in each case) of H⋯H, C⋯H/H⋯C and S⋯H/H⋯S contacts on the respective Hirshfeld surface.

acta crystallographica. section e, crystallographic communications

Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyldithiocarbamato-κ2S,S′)triphenyltin(IV) and [N-methyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV)