English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The title compound,, [Fe 4 Ni(C 3 H 6 S 2 ) 2 (C 7 H 14 S 4 )(CO) 10 ]·2CH 2 Cl 2 , is reported as a biomimic model for the active site of [FeFe]-hydrogenases. Bis(2-mercaptoeth-yl)-1,3-propane-dithio ether nickel(II) was firstly introduced into [Fe 2 (C 3 H 6 S 2 )(CO) 5 ] as an S-containing ligand. It coordinates with two [Fe 2 (C 3 H 6 S 2 )(CO) 5 ] groups, and a five-metal core complex is formed. The Fe 2 S 2 core is in a butterfly conformation. The Fe-Fe distances in the [Fe 2 (C 3 H 6 S 2 )(CO) 5 ] groups are 2.5126 (6) and 2.5086 (7) Å. The distances between the adjacent Fe and Ni atoms are 3.5322 (1) and 3.5143 (1) Å. There are intra-molecular C-H⋯O and C-H⋯S contacts present in the complex. In the crystal, the five metal cores are linked via C-H⋯O hydrogen bonds, forming columns lying parallel to (110). The di-chloro-methane solvent mol-ecules are each partially disordered over two positions and only one is linked to the five-metal core complex by a C-H⋯O hydrogen bond.

acta crystallographica. section e, crystallographic communications

Synthesis and crystal structure of decacarbonyl(μ3-3,7-dithianonane-1,9-dithiolato)bis(μ2-propane-1,3-dithiolato)nickel(II)tetrairon(II) dichloromethane disolvate