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In the title compound, [OsBr(C 10 H 14 )(C 7 H 5 O 2 )], the central Os II ion is ligated by a hexa-haptic η 6  p -cymene ring, a Br - ligand and two O atoms of a chelating tropolonate group. The p -cymene ligand presents more than one conformation, giving rise to a discrete disorder, which was modelled with two different orientations with occupancy values of 0.561 (15) and 0.439 (15). The crystal packing features C-H⋯O and C-H⋯Br hydrogen bonding. Aromatic π-π stacking inter-actions are also observed between adjacent non-benzenoid aromatic tropolone rings.

Crystal structure of bromido(η6-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ2O,O′)osmium

Crystal structure of bromido(η⁶-1-isopropyl-4-methylbenzene)(7-oxocyclohepta-1,3,5-trien-1-olato-κ²O,O′)osmium