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In the title cluster complex hexane solvate, [Ru 6 (C 30 H 32 P 2 )(CO) 22 ]·C 6 H 14 , two Ru 3 (CO) 11 fragments are linked by a Ph 2 P(CH 2 ) 6 PPh 2 bridge with the P atoms equatorially disposed with respect to the Ru 3 triangle in each case; the hexane solvent mol-ecule is statistically disordered. The Ru⋯Ru distances span a relatively narrow range, i.e . 2.8378 (4) to 2.8644 (4) Å. The hexyl chain within the bridge has an all- trans conformation. In the mol-ecular packing, C-H⋯O inter-actions between cluster mol-ecules, and between cluster and hexane solvent mol-ecules lead to a three-dimensional architecture. In addition, there are a large number of C≡O⋯π(arene) inter-actions in the crystal. The importance of the carbonyl groups in establishing the packing is emphasized by the contribution of 53.4% to the Hirshfeld surface by O⋯H/H⋯O contacts.

acta crystallographica. section e, crystallographic communications

[μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis