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The title compound, [CdNa 2 (C 8 H 4 O 4 ) 2 (C 3 H 7 NO)(H 2 O) 2 ]  n  or [CdNa 2 (1,3-bdc) 2 (DMF)(H 2 O) 2 ]  n  , is a new Cd II -Na I heterobimetallic coordination polymer. The asymmetric unit consists of one Cd II atom, two Na I atoms, two 1,3-bdc ligands, two coordinated water mol-ecules and one coordinated DMF mol-ecule. The Cd II atom exhibits a seven-coordinate geometry, while the Na I atoms can be considered to be penta-coordinate. The metal ions and their symmetry-related equivalents are connected via chelating-bridging carboxyl-ate groups of the 1,3-bdc ligands to generate a three-dimensional framework. In the crystal, there are classical O-H⋯O hydrogen bonds involving the coordinated water mol-ecules and the 1,3-bdc carboxyl-ate groups and π-π stacking between the benzene rings of the 1,3-bdc ligands present within the frameworks.

Crystal structure of poly[diaquabis(μ5-benzene-1,3-dicarboxylato)(N,N-dimethylformamide)cadmium(II)disodium(I)]

Crystal structure of poly[diaquabis(μ₅-benzene-1,3-dicarboxylato)(N,N-dimethylformamide)cadmium(II)disodium(I)]