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It is demonstrated here that tridentate imine ligands can control the nuclearity of copper(II) complexes based on the donor atoms present in the ligand. The N , N ', N ''-donating imine ligand led to a mononuclear compound, namely di-chlorido-[ N , N -dimethyl- N '-(pyridin-2-yl-methyl-idene)ethane-1,2-di-amine]copper(II) monohydrate, [CuCl 2 (C 10 H 15 N 3 )]·H 2 O, 1 , while the N , N ', O -donating imine ligand produced a binuclear metal complex, namely μ 2 -chlorido-di-chlorido-(μ 2 -2-{[2-(di-methyl-amino)-ethyl]imino-methyl}phenolato)( N , N -dimethyl-ethylene-di-amine)-dicopper(II) 0.11-hydrate, [Cu 2 (C 11 H 15 N 2 O)Cl 3 (C 4 H 12 N 2 )]·0.11H 2 O, 2 . The structure of 2 is a remarkable example of a binuclear copper(II) complex containing a single substituted 2-imino-methyl-phenolate ligand that has two copper(II) sites in square-pyramidal coordination.

acta crystallographica. section e, crystallographic communications

N,N′,N′′versus N,N′,Oimine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear CuIIcompounds