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The asymmetric unit in the title compound, [Ag(C 11 H 11 N 3 )]PF 6 ·2CH 3 CN or {[Ag L ]·PF 6 ·2CH 3 CN}  n  , L = N -(pyridin-3-ylmeth-yl)pyridin-3-amine, comprises one Ag I atom, one L ligand, two aceto-nitrile solvent mol-ecules and one PF 6  - anion disordered over two orientations in a 0.567 (11):0.433 (11) ratio. Each Ag I atom is coordinated by two pyridine N atoms from two L ligands in a slightly distorted linear coordination geometry [N-Ag-N = 170.55 (8)°]. Each L ligand bridges two Ag I ions, resulting in the formation of a zigzag chain propagating along the [101] direction. In the crystal, Ag⋯Ag contacts [3.3023 (5) Å] and inter-molecular π-π stacking inter-actions [centroid-to-centroid distance = 3.5922 (15) Å] between the pyridine rings link these chains into a corrugated layer parallel to the ([Formula: see text]01) plane. The layers are stacked with a separation of 10.4532 (5) Å, and aceto-nitrile solvent mol-ecules and PF 6  - anions as guests are inter-calated between the layers. The layers are connected through several N/C-H⋯F hydrogen bonds and P-F⋯π inter-actions [F⋯ring centroid = 3.241 (8) Å] between the layer and the inter-calated guests and between the inter-calated guests, forming a three-dimensional supra-molecular network.

acta crystallographica. section e, crystallographic communications

Crystal structure of an AgIintercalation compound:catena-poly[[silver(I)-μ-N-(pyridin-3-ylmethyl)pyridin-3-amine-κ2N:N′] hexafluoridophosphate acetonitrile disolvate]