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The synthesis and crystal structure of a monoclinic ( P 2 1 / c ) polymorph of the title compound, C 6 H 10 S 2 N 8 , are reported. The mol-ecule has pseudo-twofold rotational symmetry, with the tetra-zole rings being inclined to one another by 5.50 (6)°. In the crystal, mol-ecules are linked by C-H⋯N hydrogen bonds, forming chains propagating along [101] and enclosing R  2  2 (20) ring motifs. The chains are linked by offset π-π inter-actions involving the tetra-zole rings [inter-centroid distances vary from 3.3567 (7) to 3.4227 (7) Å], forming layers parallel to the ac plane. The crystal structure of the triclinic polymorph ( P [Formula: see text]) has been described previously [Li et al. (2011 ▸). Acta Cryst. E 67 , o1669].

A monoclinic polymorph of 1,2-bis[(1-methyl-1H-tetrazol-5-yl)sulfanyl]ethane (BMTTE)