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In the title compound, the indole ring system makes a dihedral angle of 63.56 (8)° with the plane of the anthracene ring. The conformation about the C=N bond of the –CH 2 –CH 2 –N=CH– bridge linking the two units is  E . In the crystal, the indole H atom is involved in an inter­molecular N—H⋯π inter­action with the benzene ring of the indole group, leading to the formation of chains along [010].

Crystal structure and DFT study of (E)-N-[2-(1H-indol-3-yl)ethyl]-1-(anthracen-9-yl)methanimine