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The MnBr 2  complex of  N   2 , N   6 -bis­(di- tert -butyl­phosphan­yl)pyridine-2,6-di­amine ( 1 ·MnBr 2 ) co-crystallizes with 5.69% of the monophosphine oxide analogue ( 1 O·MnBr 2 ) and two tetra­hydro­furan (THF) mol­ecules, namely { N   2 , N   6 -bis­(di- tert -butyl­phosphan­yl)pyridine-2,6-di­amine}­dibromido­manganese(II)–[bis­(di- tert -butyl­phosphan­yl)({6-[(di- tert -butyl­phosphan­yl)amino]­pyridin-2-yl}amino)­phosphine oxide]di­bromido­manganese(II)–tetra­hydro­furan (0.94/0.06/2), [MnBr 2 (C 21 H 41 N 3 P 2 )] 0.94 [MnBr 2 (C 21 H 41 N 3 OP 2 )] 0.06 ·2C 4 H 8 O. The  1 ·MnBr 2  and  1 O·MnBr 2  complexes are connected by weak N—H⋯Br hydrogen bonding into chains extending along [001] with the THF mol­ecules located between the layers formed by these chains.

acta crystallographica. section e, crystallographic communications

Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N2,N6-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue