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In the crystal of the title compound, the benzoic acid mol­ecules are linked by O—H⋯O hydrogen bonds, forming inversion dimers with(8) motifs. The dimers are linked further  via  weak C—H⋯O hydrogen bonds, and S⋯ S  and  S ⋯C contact inter­actions into a layer structure.

Crystal structure of ethylenedioxytetrathiafulvalene-4,5-bis(thiolbenzoic acid) 0.25-hydrate