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The Zn II  atoms in {Zn[S 2 CN( R )CH 2 CH 2 OH] 2 (pyridine)·pyridine}, for  R  = Me (I) and Et (II), are coordinated non-symmetrically by two di­thio­carbamate ligands and by a pyridine ligand, resulting in an NS 4  donor set that defines a distorted geometry in each case; the non-coordinating pyridine mol­ecules are connected with the Zn-containing mol­ecules  via  O—H⋯N(pyridine) hydrogen bonds. The mol­ecular packing features significant (hy­droxy)O—H⋯O(hy­droxy) hydrogen bonding, in each case leading to supra­molecular chains with zigzag (I) or helical (II) arrangements.

acta crystallographica. section e, crystallographic communications

Crystal structure of bis[N-(2-hydroxyethyl)-N-methyldithiocarbamato-κ2 S,S′](pyridine)zinc(II) pyridine monosolvate and its N-ethyl analogue