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X-ray structure analysis of hy­droxy–cineole, derived from the biotransformation of cineole, was undertaken to unambiguously determine the location and stereochemistry of the hydroxyl functionality. In the solid state, weak intra­molecular O—H⋯O hydrogen bonding is present, causing the mol­ecules to arrange in spiral chains.

Structural elucidation of a hydroxy–cineole product obtained from cytochrome P450 monooxygenase CYP101J2 catalysed transformation of 1,8-cineole