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The solvated title compound, [ZnCl 2 (C 20 H 17 BrN 2 )]·0.5CH 2 Cl 2 , comprises a bidentate imino-pyridine ligand and two Cl atoms bound to a zinc 2+ cation in a distorted tetra-hedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C-C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C-H⋯Cl hydrogen bonds between the complex mol-ecules and the disordered solvent mol-ecules (occupancy = 0.5), no further significant inter-molecular inter-actions are observed.

acta crystallographica. section e, crystallographic communications

Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate