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In the title compound, [Co(C 57 H 52 N 6 O 6 )], the central Co II atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) ( C  a ), 0.20 (10) ( C  b ), 0.24 (4) ( C  m ) and 0.18 (10) Å ( C  av ), respectively. The axial Co-O bond length is 2.3380 (15) and the average Co-N p bond length is 1.968 (5) Å. Intra-molecular N-H⋯O and inter-molecular C-H⋯π inter-actions are observed.

Crystal structure of (5-{3-[(1,4,7,10,13-pentaoxa-16-azacyclooctadecan-16-yl)carbonylamino]phenyl}-10,15,20-triphenylporphyrinato)cobalt(II)