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The title compound, [Sn(CH 3 ) 2 (C 5 H 8 NOS 2 ) 2 ], has the Sn IV atom bound by two methyl groups which lie over the weaker Sn-S bonds formed by two asymmetrically chelating di-thio-carbamate ligands so that the coordination geometry is skew-trapezoidal bipyramidal. The most prominent feature of the mol-ecular packing are secondary Sn⋯S inter-actions [Sn⋯S = 3.5654 (7) Å] that lead to centrosymmetric dimers. These are connected into a three-dimensional architecture via methyl-ene-C-H⋯S and methyl-C-H⋯O(morpholino) inter-actions. The Sn⋯S inter-actions are clearly evident in the Hirshfeld surface analysis of the title compound along with a number of other inter-molecular contacts.

Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ2S,S′)tin(IV): crystal structure and Hirshfeld surface analysis

Secondary bonding in dimethylbis(morpholine-4-carbodithioato-κ²S,S′)tin(IV): crystal structure and Hirshfeld surface analysis