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The title compound, (C 6 H 11 ) 3 PS (systematic name: tri-cyclo-hexyl-λ 5 -phosphane-thione), is a triclinic ( P -1, Z ' = 1) polymorph of the previously reported ortho-rhom-bic form ( Pnma , Z ' = 1/2) [Kerr et al. (1977 ▸). Can. J. Chem . 55 , 3081-3085; Reibenspies et al. (1996 ▸). Z. Kristallogr . 211 , 400]. While conformational differences exist between the non-symmetric mol-ecule in the triclinic polymorph, cf . the mirror-symmetric mol-ecule in the ortho-rhom-bic form, these differences are not chemically significant. The major feature of the mol-ecular packing in the triclinic polymorph is the formation of linear chains along the a axis sustained by methine-C-H⋯S(thione) inter-actions. The chains pack with no directional inter-actions between them. The analysis of the Hirshfeld surface for both polymorphs indicates a high degree of similarity, being dominated by H⋯H ( ca 90%) and S⋯H/H⋯S contacts.

A triclinic polymorph of tricyclohexylphosphane sulfide: crystal structure and Hirshfeld surface analysis