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The title compound, [Cd 2 (C 8 H 8 NS 2 ) 4 ], is a centrosymmetric dimer with both chelating and μ 2 -tridentate di-thio-carbamate ligands. The resulting S 5 donor set defines a Cd II coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C-H⋯S and C-H⋯π inter-actions, which generate a three-dimensional network. The influence of these inter-actions, along with intra-dimer π-π inter-actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.

acta crystallographica. section e, crystallographic communications

Bis(μ2-N-methyl-N-phenyldithiocarbamato)-κ3S,S′:S;κ3S:S,S′-bis[(N-methyl-N-phenyldithiocarbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis