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In the title cobalt(II) coordination polymer with isobutyrate ligands, {[Co{CH(CH 3 ) 2 CO 2 } 2 (H 2 O)]·H 2 O}  n  , the Co 2+ ion is hexa-coordinated in a slightly distorted octa-hedral coordination environment defined by two O atoms from two bridging water mol-ecules and four O atoms from four bridging carboxyl-ate ligands. The carboxyl-ates adopt two different coordination modes, μ-(κ 2  O : O ') and μ-(κ 2  O : O ), forming a one-dimensional polymeric chain extending along [010]. The intra-chain cobalt⋯cobalt separation is 3.2029 (2) Å. The polymeric chains are linked by hydrogen bonds involving the water mol-ecules of solvation, giving a two-dimensional network structure lying parallel to (100).

acta crystallographica. section e, crystallographic communications

Crystal structure of a CoIIcoordination polymer:catena-poly[[μ-aqua-bis(μ-2-methylpropanoato)-κ2O:O′;κ2O:O-cobalt(II)] monohydrate]