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In the title polymeric complex, [Fe{OS(CH 3 ) 2 } 2 {Ag(CN) 2 } 2 ], the Fe II cation is located at an inversion centre and is coordinated by four cyanide (CN - ) anions and two dimethyl sulfoxide mol-ecules in a slightly compressed N 4 O 2 octa-hedral geometry, the Ag I cation is C-coordinated by two CN - anions in a nearly linear geometry. The CN - anions bridge the Fe II and Ag I cations to form a two-dimensional polymeric structure extending parallel to (102). In the crystal, the nearest Ag⋯Ag distance between polymeric sheets is 3.8122 (12) Å. The crystal studied was a twin with a contribution of 0.2108 (12) for the minor component.

Crystal structure of poly[tetra-μ2-cyanido-1:2κ8N:C-bis(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]

Crystal structure of poly[tetra-μ₂-cyanido-1:2κ⁸N:C-bis(dimethyl sulfoxide-1κO)diargentate(I)iron(II)]