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The tetra-nuclear title complex, [Ni 4 (C 14 H 11 NO 2 ) 4 (CH 3 OH) 4 ]·0.8CH 3 OH, has a distorted cubane topology shaped by four Schiff base ligands. The cubane [Ni 4 (μ 3 -O 4 )] core is formed via the O atoms from the Schiff base ligands. The octa-hedrally coordinated Ni II ions occupy alternating vertices of the cube. Each Ni II ion is coordinated by one O , N , O '-tridentate dianionic ligand, two O atoms of oxidophenyl groups from adjacent ligands and the O atom of a coordinating methanol mol-ecule. The cubane core is stabilized via an intra-molecular O-H⋯O hydrogen bond between the hy-droxy group of the coordinating methanol mol-ecules and the phenolate O atom of the aldehyde Schiff base fragment. Additional stabilization is obtained via intra-molecular C-H⋯O hydrogen bonds involving aromatic C-H groups and the oxygen atoms of adjacent methanol mol-ecules. In the crystal, complex mol-ecules are linked into chains parallel to the c axis via weak C-H⋯O hydrogen bonds. The partial-occupancy disordered methanol solvent mol-ecule has a site occupancy of 0.8 and is linked to the tetra-nuclear unit via an inter-molecular C-H⋯O hydrogen bond involving a phenolate O atom.

acta crystallographica. section e, crystallographic communications

A tetranuclear cubane-like nickel(II) complex with a tridentate salicylideneimine Schiff base ligand: tetrakis[μ<sub>3</sub>-4-methyl-<i>N</i>-(2-oxidophenyl)salicylideneiminato]tetrakis[methanolnickel(II)] methanol 0.8-solvate

A tetranuclear cubane-like nickel(II) complex with a tridentate salicylideneimine Schiff base ligand: tetrakis[μ3-4-methyl-N-(2-oxidophenyl)salicylideneiminato]tetrakis[methanolnickel(II)] methanol 0.8-solvate

A tetranuclear cubane-like nickel(II) complex with a tridentate salicylideneimine Schiff base ligand: tetrakis[μ₃-4-methyl-N-(2-oxidophenyl)salicylideneiminato]tetrakis[methanolnickel(II)] methanol 0.8-solvate