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The reaction of silver nitrate and cafenstrole ( N , N -diethyl-3-mesitylsulfonyl-1 H -1,2,4-triazole-1-carboxamide), a triazole herbicide, leads to the title coordination polymer, [Ag(NO 3 )(C 16 H 22 N 4 O 3 S)]  n  , whose asymmetric unit comprises one cafenstrole ligand mol-ecule, one Ag I atom and one nitrate ion. The Ag I atom, with a distorted trigonal-pyramidal environment, is coordinated by one nitro-gen atom of a triazole ring, two oxygen atoms of a nitrate ion and one oxygen atom of a neighboring nitrate ion. The coordination bonds between silver and oxygen atoms give rise to a one-dimensional (1D) coordination polymer structure along [001]. The dihedral angle between the planes of the triazole and benzene rings is 87.13 (11)°. In the crystal, the coordination polymer is stabilized by C-H⋯O hydrogen bonds and C-H⋯π inter-actions, resulting in a three-dimensional architecture.

acta crystallographica. section e, crystallographic communications

Crystal structure ofcatena-poly[[(N,N-diethyl-3-mesitylsulfonyl-1H-1,2,4-triazole-1-carboxamide-κN1)silver(I)]-μ-nitrato-κ3O,O′:O]