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The asymmetric unit of the title compound, [Ni(NCS) 2 (C 5 H 4 ClN) 2 (H 2 O) 2 ], consists of one nickel(II) cation that is located on a center of inversion and one thio-cyanate anion, one water mol-ecule and one 2-chloro-pyridine ligand all occupying general positions. The Ni II cation is octa-hedrally coordinated by two terminal N-bound thio-cyanato ligands, two aqua ligands and two N-bound 2-chloro-pyridine ligands into discrete complexes. Individual complexes are linked by inter-molecular O-H⋯S and O-H⋯Cl hydrogen-bonding inter-actions into a layered network extending parallel to the bc plane. Weak inter-actions of types C-H⋯S and C-H⋯Cl consolidate the crystal packing.

Crystal structure of diaquabis(2-chloropyridine-κN)bis(thiocyanato-κN)nickel(II)