English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

The crystal and mol-ecular structures of two tri-phenyl-tin di-thio-carbamates, [Sn(C 6 H 5 ) 3 (C 16 H 16 NS 2 )], (I), and [Sn(C 6 H 5 ) 3 (C 7 H 14 NO 2 S 2 )], (II), are described. In (I), the di-thio-carbamate ligand coordinates the Sn IV atom in an asymmetric manner, leading to a highly distorted trigonal-bipyramidal coordination geometry defined by a C 3 S 2 donor set with the weakly bound S atom approximately trans to one of the ipso -C atoms. A similar structure is found in (II), but the di-thio-carbamate ligand coordinates in an even more asymmetric fashion. The packing in (I) features supra-molecular chains along the c axis sustained by C-H⋯π inter-actions; chains pack with no directional inter-actions between them. In (II), supra-molecular layers are formed, similarly sustained by C-H⋯π inter-actions; these stack along the b axis. An analysis of the Hirshfeld surfaces for (I) and (II) confirms the presence of the C-H⋯π inter-actions but also reveals the overall dominance of H⋯H contacts in the respective crystals.

acta crystallographica. section e, crystallographic communications

[N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis