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The title solvated complex, [FePd(C 5 H 5 )(C 12 H 13 N 2 S)Cl(C 18 H 15 P) 2 ]PF 6 ·2CHCl 3 , bearing a chiral ferrocenyl pyrrolo-imidazolyl-idene N -heterocyclic carbene (NHC) ligand, was synthesized by oxidative addition of a chloro-imidazolium salt to Pd(PPh 3 ) 4 . The Pd II ion is coordinated in a slightly distorted square-planar coordination geometry, with the Cl atom trans to the coordinating C atom of the pyrrolo-imidazolyl-idene ligand. The complex features a pendant thio-ether group that is not involved in coordination to Pd. In the crystal, weak C-H⋯F and C-H⋯π inter-actions connect the components of the structure, forming chains propagating along [1-10]. The fused pyrrolidine ring is in an envelope conformation, and the flap atom was refined as disordered over two sets of sites, with occupancies of 0.77 (4) and 0.23 (4).

acta crystallographica. section e, crystallographic communications

(+)-trans-Chlorido{2-[(Rp)-2-(methylsulfanyl)ferrocenyl]-2,5,6,7-tetrahydropyrrolo[1,2-c]imidazol-3-ylidene}bis(triphenylphosphane-κP)palladium(II) hexafluoridophosphate dichloroform disolvate