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The crystal structure of the title compound, [Mn(C3H7NO)6][{Mn(C3H7NO)5}2(μ-P2W18O62)]·2C3H7NO, reveals that the Wells-Dawson-type polyanion [P2W18O62](6-), through terminal O atoms from the belts, bridges two Mn(II) octa-hedral complexes. In the complex anion [{Mn(dmf)5}2(μ-P2W18O62)](2-), located around a twofold rotation axis, the Mn(II) ions are coordinated by five O atoms from di-methyl-formamide (dmf) ligands and to a terminal O atom from the [P2W18O62](6-) polyanion. Another Mn(II) ion, located on an inversion centre, is coordinated by six O atoms from the dmf ligands and forms the [Mn(dmf)6](2+) cation. The crystal components are connected through numerous weak C-H⋯O hydrogen bonds to construct a three-dimensional network.

acta crystallographica. section e, crystallographic communications

Crystal structure of hexakis(dimethylformamide-κO)manganese(II) decakis(dimethylformamide)-1κ5O,2κ5O-[μ-octadecatungstodiphosphato(V)-κO:κO′]dimanganate(II) dimethylformamide disolvate