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The title dinuclear Cu(II) complex, [Cu2(C17H13N2O2)4], is located on an inversion centre. The Cu(II) atoms are each five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from two bidentate ligands and one bridging O atom from another ligand. In the dinuclear complex, the Cu⋯Cu separation is 3.366 (3) Å. In the crystal, complex mol-ecules are linked via weak C-H⋯O hydrogen bonds, forming a layer parallel to (-101).

acta crystallographica. section e, crystallographic communications

Crystal structure of bis{μ-1-[(E)-(3-methoxyphenyl)diazenyl]naphthalen-2-olato-κ3N2,O:O}bis({1-[(E)-(3-methoxyphenyl)diazenyl]naphthalen-2-olato-κ2N2,O}copper(II))