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The title compound, [Re2(C3H7COO)2Cl4{(CH3)2SO}2], comprises binuclear complex mol-ecules [Re-Re = 2.24502 (13) Å] involving cis-oriented double carboxyl-ate bridges, four equatorial chloride ions and two weakly bonded O atoms from dimethyl sulfoxide ligands in the axial positions at the Re(III) atoms. In the crystal, mol-ecules are linked into corrugated layers parallel to (101) by very weak C-H⋯Cl and C-H⋯O hydrogen-bonding inter-actions. C-H⋯Cl hydrogen bonding provides the links between layers to consolidate a three-dimensional framework.

Crystal structure of di-μ-isobutyrato-κ4O:O′-bis[cis-dichlorido(dimethyl sulfoxide-κS)rhenium(III)]

Crystal structure of di-μ-isobutyrato-κ⁴O:O′-bis[cis-dichlorido(dimethyl sulfoxide-κS)rhenium(III)]