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The crystal structure of the dinuclear arene ruthenium title complex, [Ru2(C6H5OS)(C7H7S)2(C10H14)2]BF4, shows the two Ru(II) atoms to be bridged by two benzyl-thio-pheno-late units and one 4-hy-droxy-thio-pheno-late unit, with the remaining three coordination sites of each Ru(II) atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF4 (-) counter-anion is surrounded by four cationic dinuclear complexes, showing an O-H⋯F hydrogen bond and several weak C-H⋯F inter-actions. This is the first example of an X-ray analysis of a mixed dinuclear tri-thiol-ate arene ruthenium(II) complex.

acta crystallographica. section e, crystallographic communications

Crystal structure of (μ-4-hydroxybenzenethiolato-κ2S:S)bis(μ-phenylmethanethiolato-κ2S:S)bis[(η6-1-isopropyl-4-methylbenzene)ruthenium(II)] tetrafluoridoborate